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1st July 2007
 


Yttrium single crystal 39Y88.905

Discovered in 1794 by J Gadolin at Åbo, Finland.

  [Nmed after Ytterby, Sweden]
  French: yttrium
  German: yttrium
  Italian: ittrio
  Spanish: ytrio

Description: Yttrium is a soft, silvery-white metal that is stable in air due to the formation of an oxide film on its surface. It burns if ignited, and is attacked by water and forms hydrogen. Yttrium is used in various ways: to give red colours in TV screens, in X-ray filters, superconductors and for superalloys.


Metal single crystal properties
State: single crystal
Crystal structure: hexagonal
Production method: Floating zone
Standard size: diameter 4mm
thickness 1mm
Orientation: (0001)
Orientation accuracy: <2°, <1°, <0.5° or <0.1°
Polishing: as cut, one or two sides polished
Roughness of surface: <0.03µm
Purity: 99.95%


Further Materials properties
Crystal structure: (cell dimensions/pm), space group
a-Y h.c.p. (a=364.74, c=573.06), P63/mmc
b-Y b.c.c. (a=411), Im3m
T(a->
b)=1763 K
X-ray diffractions mass absorption coefficients: CuKa 134 (µ/r) / cm2g-1
MoKa 100 (µ/r) / cm2g-1
Neutron scattering length: 0.775 b/10-12 cm
Thermal neutron capture cross-section: 1.28 sa / barns
Density: 4.47 g/cm3
Melting point: 1521.85 °C / 1795 °K
Boiling point: 3337.85 °C / 3611 °K
Molar volume: 19.89 cm3
Thermal conductivity: 17.2 [300 K] Wm-1K-1
Coefficient of linear thermal expansion: 10.6 x 10-6 K-1
Electrical resistivity: 57.0x10-8 [298 K] Wm
Mass magnetic susceptibility: +2.70 x 10-8(s) kg-1m3
Young's modulus: 66.3 GPa
Rigidity modulus: 25.5 GPa
Bulk modulus: n.a. GPa
Poisson's ratio: 0.265 GPa
Radii: Y3+ 106; atomic 181; covalent 162
Electronegativity: 1.22 (Pauling); 1.11 (Allred); 3.19 eV (absolute)
Effective nuclear charge: 3.00 (Slater); 6.26 (Clementi); 8.72 (Froese-Fischer)
Number of Isotopes (incl. nuclear isomers): 32
Issotope mass range: 80 -> 99


Biological data
Biological role: none
Toxicity  
Toxic intake: n.a.
Lethal intake: c. 15 g only one case reported)
Hazards: Bismuth is regarded as one of the less toxic heavy metals and it is commonly used as a medicine for stomach upsets. Excess bismuth can cause mild kidney damage
Level in humans  
Blood: 0.016 mg dm-3
Bone: <0.2 p.p.m.
Liver: 0.015 - 0.33 p.p.m.
Muscle: 0.32 p.p.m.
Daily dietary intake : 0.005 - 0.02 mg
Total mass of element in average
[70 kg] person:
< 0.5 mg


Geological data
Minerals: Many minerals are known, and aluminium is present in many other minerals
 Mineral  Formula  Density  Hardness  Crystal apperance
 Bastnäsite-Y  (Y, Ce)Co3F  4.0  4 - 4.5  tri. translucent brick-red
 Fergusonite  YNbO4  5.7  5.5 - 6.5  tet., vitreous, sub-metallic black
 Gadolinite  Be2FeY2Si2O10  4.4  6.5 - 7  mon., vit./greasy greenish-black
 Polycrase-Y  Y(Ti, Nb)2(O, OH)6  5.0  5.5 - 6  orth., sub-metallic black
 Samarskite  AlO(OH)  3.3 - 3.5  6.5 - 7  orth., vit./resinous
 Xenotime/TD>  YPO4  4.8  4 - 5  tet., vit./resinous yellow-brown
Chief ore: xenotime, bastnäsite, fergusonite, samarskite
World production: 400 tonnes/year
Main mining areas: xenitine in USA, bastnäsite in Russia, fergusonite in Norway, Russia, Madagascar
Reserves: c. 9 x 106 tonnes
Specimen: available as chieps, ingots or powder. Safe.
Abundances  
Sun: 125 (relative to H = 1 x 1012)
Earth's crust: 30 p.p.m.
Seawater: 9 x 10-6 p.p.m.
Residence time:: n.a.
Oxidation state: III

Other sizes and specifications on request


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