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Last Update
1st July 2007
 


Iron single crystal 26Fe55.847

Known to ancient civilizations.

  [Anglo-Saxon: iron; Latin: ferrum]
  French: fer
  German: eisen
  Italian: ferro
  Spanish: hierro

Description: Iron, when absolutely pure, is lustrous, silvery and soft (workable). This is the most important of all the metals and it is used chiefly as steel in which there is carbon (up to 1.7%). Stainless steels are alloys with other metals, mainly nickel. Iron rusts in damp air and dissolves readily in dilute acids. Its uses are legion.


Metal single crystal properties
State: single crystal  
Crystal structure: bcc  
Production method: Strain annealing  
Standard size: diameter 6-10mm
thickness 1-2mm
 
Orientation: (100), (110) and (111)  
Orientation accuracy: <2°, <1°, <0.5° or <0.1°  
Polishing: as cut, one or two sides polished  
Roughness of surface: <0.03µm  
Purity: 99.98%  
Typical analysis (ppm): Ag < 0.1
Al < 0.1
As < 0.1
C 12
Ca 0.8
Cl 0.8
Co 2.6
Cu 0.6
Cr 1.6
K 1.8
Mg 0.87
Mo < 0.1
N 10.0
Na 1.6
Ni < 0.1
O 30.0
P 0.7
S 2.6
Si 2.9
Ti 1.4
V 0.1
Zn 1.9
Fe balance


Further Materials properties
Crystal structure: (cell dimensions/pm), space group
a-Fe b.c.c. (a=286.645),Im3m
b-Fe not true allotrope
g-Fe c.c.p. (a=364.68), Fm3m
d-Fe b.c.c. (a=293.22), Im3m
T(a -> a)=1183 K
T(g -> d)=1663 K
X-ray diffractions mass absorption coefficients: CuKa 308 (µ/r) / cm2g-1
MoKa 38.5 (µ/r) / cm2g-1
Neutron scattering length: 0.954 b/10-12 cm
Thermal neutron capture cross-section: 2.56 sa / barns
Density: 7.86 g/cm3
Melting point: 1534.85 °C / 1808 °K
Boiling point: 2749.85 °C / 3023 °K
Molar volume: 7.09 cm3
Thermal conductivity: 80.2 [300 K] Wm-1K-1
Coefficient of linear thermal expansion: 12.3 x 10-6 K-1
Electrical resistivity: 9.71x10-8 [293 K] Wm
Mass magnetic susceptibility: ferromagnetic
Young's modulus: 152.3 GPa (cast); 208 GPa (steel)
Rigidity modulus: 60.0 GPa (cast); 81 GPa (steel)
Bulk modulus: 109.5 GPa (cast); 160 GPa (steel)
Poisson's ratio: 0.27 GPa (cast); 0.27 GPa (steel)
Radii: Fe3+ 67; Fe2+ 82; atomic 124; covalent 116; van der Waals n.a.
Electronegativity: 1.83 (Pauling); 1.64 (Allred); 4.06 eV (absolute)
Effective nuclear charge: 3.75 (Slater); 5.43 (Clementi); 7.40 (Froese-Fischer)
Number of Isotopes (incl. nuclear isomers): 16
Issotope mass range: 49 -> 63


Biological data
Biological role: Essential to all species
Toxicity  
Toxic intake: 200 mg, Iron (II) compounds are more toxic than iron (III)
Lethal intake: 7 - 35 g
Hazards: Iron dust poses a moderate fir or explosion hazad: chronic exposure causes iron pneumoconiosis (welder lung). Iron deficiency leads to anaemia, but excess iron in the body causes liver and kidney damage. Some iron compounds are suspected carcinogens.
Level in humans  
Blood: 447 mg dm-3
Bone: 3 - 380 p.p.m.
Liver: 250 - 1400 p.p.m.
Muscle: 180 p.p.m.
Daily dietary intake : 6 - 40 mg
Total mass of element in average
[70 kg] person:
4.2 mg


Geological data
Minerals: Many iron minerals are known, only a few of which are listed.
 Mineral  Formula  Density  Hardness  Crystal apperance
 Goethite  a-FeO(OH)  4.28  5 - 5.5  orth., met. earthy brown
 Hematite  Fe2O3  5.26  5 - 6  rhom., met. earth grey
 Lepidocrocite  g-FeO(OH)  4.09  5  orth., met. reddish-brown
 Magnetite  Fe3O4  5.175  5.5 - 6.5  cub., met. black
 Siderite  FeCO3  3.96  4  rhom., vit. yellow-brown
Chief ore: hematite, magnetite, goethite, lepididocrocite, siderite
World production: 7.16 x 108 tonnes/year
Main mining areas: USA, Canada, Sweden, South Africa, Russia, India, Japan
Reserves: 1.1 x 1011 tonnes
Specimen: available as chips, filings, foil, granules, and wire. Safe.
Abundances  
Sun: 3.16 x 107 (relative to H = 1 x 1012)
Earth's crust: 41000 p.p.m.
Seawater:  
  Atlantic surface: 1 x 10-4 p.p.m.
  Atlantic deep: 4 x 10-4 p.p.m.
  Pacific surface: 0.1 x 10-8 p.p.m.
  Pacific deep: 1 x 10-8 p.p.m.
Residence time:: 98 years
Classification: recycled
Oxidation state: III

Other sizes and specifications on request


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