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Last Update
1st July 2007
 


Rhenium single crystal 75Re186.2

Discovered in 1925 by W. Noddack, Ida Tacke and O. Berg at Berlin, Germany.

  [Greek: lithos = stone]
  French: lithium
  German: lithium
  Italian: litio
  Spanish: litio

Description: Rhenium is a silvery metal, but is usually obtained as a grey powder. It resists corrosion but slowly tarnishes in moist air. Rhenium dissolves in HNO3 an H2SO4. It is used in filaments, thermistors and catalysts.


Metal single crystal properties
State: Single crystal  
Crystal structure: hexagonal  
Production method: Floating zone  
Standard size: diameter 6mm
thickness 1-2mm
 
Orientation: (0001), (1-100) and (11-20)  
Orientation accuracy: <2°, <1°, <0.5° or <0.1°  
Polishing: as cut, one or two sides polished  
Roughness of surface: <0.03µm  
Purity: 99.99%  
Typical analysis (ppm): Ag < 0.10
Al 2.00
Au 0.90
C 15.0
Cl 3.00
Co 0.20
Cr 2.50
Cu 0.40
Fe 15.0
H < 1.00
Mg 0.03
Mn 1.00
Mo 2.00
N < 5.00
Na 0.20
Ni < 1.00
Pt 10.0
O 6.00
Si 10.0
Ti 1.00
Ta 0.30
V 0.20
W 10.0
Zr 2.00
Rh balance


Further Materials properties
Crystal structure: (cell dimensions/pm), space group
h.c.p. (a=276.09), c=445.76), P63/mmc
X-ray diffractions mass absorption coefficients: CuKa 179 (µ/r) / cm2g-1
MoKa 103 (µ/r) / cm2g-1
Neutron scattering length: 0.92 b/10-12 cm
Thermal neutron capture cross-section: 89.7 sa / barns
Density: 12.4 g/cm3
Melting point: 3179.85 °C / 3453 °K
Boiling point: 5626.85 °C / 5900 °K
Molar volume: 8.86 cm3
Thermal conductivity: 47.9 [300 K] Wm-1K-1
Coefficient of linear thermal expansion: 6.63 x 10-6 K-1
Electrical resistivity: 19.3x10-8 [293 K] Wm
Mass magnetic susceptibility: +4.56 x 10-9(s) kg-1m3
Young's modulus: 466 GPa
Rigidity modulus: 181 GPa
Bulk modulus: 334 GPa
Poisson's ratio: 0.26 GPa
Radii: Re7+ 60; Re6+ 61; Re4+ 72; atomic 137; covalent 128
Electronegativity: 1.9 (Pauling); 1.46 (Allred); 4.02 eV (absolute)
Effective nuclear charge: 3.60 (Slater); 10.12 (Clementi); 14.62 (Froese-Fischer)
Number of Isotopes (incl. nuclear isomers): 34
Issotope mass range: 162 -> 192


Biological data
Biological role: none
Toxicity: Not established, but believed to be low.
Toxic intake: n.a.
Lethal intake: LD50 (ReCl3, intraperitoneal, mouse)= 280 mg kg-1
Hazards: There are no reported cases of humans beeing affected by rhenium. Like other powdered metals, rhenium dust could pose a moderate fire or explosion hazard.
Level in humans  
Organs: n.a., but very low
Daily dietary intake : n.a.
Total mass of element in average
[70 kg] person:
n.a., but very low


Geological data
Minerals: Rhenium does not occur in nature as the free metal, nor has a distinct rhenium mineral species been found. Gadolinite (see beryllium) and molybdenite (see molybdenum) may contain up to 0.2% rhenium.
Chief ore: Rhenium is extracted from the flue dusts of molybdenum smelters.
World production: 4.5 tonnes/year
Main mining areas: see molybdenum
Reserves: 3500 tonnes
Specimen: available as foil, powder, ribbon or wire. CARE !
Abundances  
Sun: <2 (relative to H = 1 x 1012)
Earth's crust: 4 x 10-4 p.p.m.
Seawater: 4 x 10-6 p.p.m.
Oxidation state: III

Other sizes and specifications on request


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