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Last Update
1st July 2007
 


Ruthenium single crystal 44Ru101.07

Ruthenium was discovered in 1808 by J.A. Sniadecki at the University of Vilno, Poland. Rediscovered in 1828 by G.W. Osann at the University of Tartu, Russia.

  [Latin: ruthenia = Russia]
  French: ruthénium
  German: ruthenium
  Italian: rutenio
  Spanish: rutenio

Description: Ruthenium is a lustrous, silvery metal of the so-called platinum group. It is unaffected by air, water and acids, but dissolves in molten alkalis. Ruthenium is used to harden platinum an palladium metals, and as a catalyst.


Metal single crystal properties
State: single crystal  
Crystal structure: hexagonal  
Production method: Floating zone  
Standard size: diameter 6-8mm
thickness 1-2mm
 
Orientation: (0001), (+1-100) and (11-20)  
Orientation accuracy: <2°, <1°, <0.5° or <0.1°  
Polishing: as cut, one or two sides polished  
Roughness of surface: <0.03µm  
Purity: 99.99%  
Typical analysis (ppm): Ag < 1
Au 2
Ca 17
Cu 2
Cr 3
Fe 10
Ir 25
Mg 3
Mn < 1
Os 40
Pb 2
Ru balance


Further Materials properties
Crystal structure: (cell dimensions/pm), space group
h.c.p. (a=270.58, c=428.11), P63/mmc hexagonal
X-ray diffractions mass absorption coefficients: CuKa 183 (µ/r) / cm2g-1
MoKa 21.1 (µ/r) / cm2g-1
Neutron scattering length: 0.721 b/10-12 cm
Thermal neutron capture cross-section: 2.56 sa / barns
Density: 12.2 g/cm3
Melting point: 2309.85 °C / 2583 °K
Boiling point: 3899.85 °C / 4173 °K
Molar volume: 8.14 cm3
Thermal conductivity: 117 [300 K] Wm-1K-1
Coefficient of linear thermal expansion: 9.1 x 10-6 K-1
Electrical resistivity: 7.6x10-8 [273 K] Wm
Mass magnetic susceptibility: +5.37 x 10-9(s) kg-1m3
Young's modulus: 432 GPa
Rigidity modulus: 173 GPa
Bulk modulus: 286 GPa
Poisson's ratio: 0.25 GPa
Radii: Ru5+ 54; Ru4+ 65; Ru3+ 77; atomic 134; covalent 124
Electronegativity: 2.2 (Pauling); 1.42 (Allred); 4.5 eV (absolute)
Effective nuclear charge: 3.75 (Slater); 7.45 (Clementi); 10.57 (Froese-Fischer)
Number of Isotopes (incl. nuclear isomers): 20
Issotope mass range: 92 -> 110


Biological data
Biological role: none
Toxicity  
Toxic intake: most ruthenium compunds are poisonous
Lethal intake: LD50 (RuO2, oral, rat)= 4580 mg kg-1
Hazards: Ingested ruthenium is retained in the bones for a long time. The volatile oxide, RuO4 is highly toxic by inhalation.
Level in humans  
Organs: n.a., but very low
Daily dietary intake : n.a
Total mass of element in average
[70 kg] person:
n.a.


Geological data
Minerals: Few minerals as such; ruthenium metal is found in the free state, sometimes alloyed with osmium and iridium.
 Mineral  Formula  Density  Hardness  Crystal apperance
 Ruthenarsenite  (Ru, Ni) As  10  6  orth., met. orange-brown
 Ruthenium  Ru  12.2  6.5  hex., met. white
Chief ore: from the wastes of nickel refining.
World production: 0.12 tonnes/year
Main mining areas: South Africa, Russia, Canada, USA and Zimbabwe
Reserves: n.a.
Specimen: available as powder or sponge. WARNING !
Abundances  
Sun: 67.6 (relative to H = 1 x 1012)
Earth's crust: c. 0.001 p.p.m.
Seawater: n.a., but minute

Other sizes and specifications on request


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